Direct Michael Additions of Silyl Groups to α,β‐Unsaturated β‐Arylketones and an α‐Benzylidenelactone with Mixtures Obtained from Copper(I) Cyanide, Butyllithium and Chlorosilanes

This publication has 10 references indexed in Scilit:

• Diastereoselective conjugate addition of lithium methylcyanocuprate to the chiral isoprene units 2-(R)- and (S)-benzyloxy-2,5-dihydro-4-furancarbox-aldehyde. Total synthesis of (−)- and (+)-botryodiplodin and (+)- and (−)-epibotryodiplodin.
  Tetrahedron Letters, 1987
• Reactions of Chiral 2‐(tert‐Butyl)‐2H,4H‐1,3‐dioxin‐4‐ones Bearing Functional Groups in the 6‐Position and Diastereoselective Catalytic Hydrogenation to cis‐2,6‐Disubstituted 1,3‐Dioxan‐4‐ones
  Helvetica Chimica Acta, 1987
• A reactivity umpolung route to cyclic homoenolate aldol products α-alkoxyorganocuprate conjugate additions
  Tetrahedron Letters, 1987
• Trimethylsilyl chloride/tetramethylethylenediamine facilitated additions of organocopper reagents (RCu) to enones
  Tetrahedron Letters, 1987
• Organocopper conjugate addition reaction in the presence of trimethylchlorosilane
  Tetrahedron Letters, 1986
• 1,3‐Dioxanone Derivatives from β‐Hydroxy‐carboxylic Acids and Pivalaldehyde. Versatile Building Blocks for Syntheses of Enantiomerically Pure Compounds. A Chiral Acetoacetic Acid Derivative Preliminary Communication
  Helvetica Chimica Acta, 1986
• Me3SiCl/HMPA accelerated conjugate addition of catalytic copper reagent. Stereoselective synthesis of enol silyl ether of aldehyde
  Tetrahedron Letters, 1986
• The synthesis and stereoselective conjugate addition reactions of α-alkoxyorganocuprate reagents
  Tetrahedron Letters, 1986
• Evidence for a reversible d, π-complexation, β-cupration sequence in the conjugate addition reaction of Gilman reagents with α,β-enones.
  Tetrahedron Letters, 1985
• Conjugate addition of trimethysilyllithium. A preparation of 3-silyl ketones
  The Journal of Organic Chemistry, 1976