Large binding constant differences between aromatic and aliphatic substrates in positively charged cavities indicative of higher order electric effects
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 580-581
- https://doi.org/10.1039/c39890000580
Abstract
Aliphatic substrates show, in comparison to aromatic substrates of similar shape, up to 60 times lower binding constants with a cyclophane bearing +N charges on the inside of the cavity; much smaller differences are observed with the same cyclophane bearing no charges in the vicinity of the substrate.Keywords
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