Cyclometallation reactions. XV. ortho-Metallation of a sulphur-donor ligand
- 1 January 1975
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 28 (10) , 2307-2310
- https://doi.org/10.1071/ch9752307
Abstract
The reaction between benzyl methyl sulphide and Mn(CH2Ph)(CO)5 affords the ortho-metallated-complex Mn(C6H4CH2SMe)(CO)4. Some other, non- metallated complexes of the sulphur-donor ligand with ruthenium and palladium are described; with rhenium, a complex disproportionation reaction occurs, apparently giving mixed [Re(CO)3(SR)]4 (R = Me, Ph or CH2Ph) complexes.Keywords
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