Theory of E.P.R. in low-spin ferric haemoproteins
- 1 January 1971
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 21 (1) , 135-139
- https://doi.org/10.1080/00268977100101251
Abstract
Difficulty is found in fitting experimental g values for low-spin ferric haemoproteins to formulae based on a pure t 2 5 configuration. This is discussed and it is shown that it is almost certainly mainly due to neglect of configuration interaction with excited t 2 4 e states, a mechanism which was originally discussed by Thornley [8] for octahedral iridium complexes.Keywords
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