Stereoselective reductive hydroxymethylation of an annulated sugar derivative via radical cyclisation
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 1,p. 27-29
- https://doi.org/10.1039/p19920000027
Abstract
Addition of a silylmethylene and hydride radical to the carbon–carbon double of two allylic silyl ethers derived from annulated carbohydrates has been shown to occur in an anti fashion.Keywords
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