Molecular association in a silver(I) complex of a planar macrocyclic ligand. X-Ray crystal structure of a binuclear silver(I) complex
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 370-371
- https://doi.org/10.1039/c39770000370
Abstract
In the dimeric complex [Ag(2,3,2-N5)]2(ClO4)2, two near-planar [Ag(2,3,2-N5)]+ cations are associated in a face-to-face fashion such that each metal ion interacts axially [at 2·748(10)Å] with one trigonally hybridised and co-ordinatively saturated nitrogen atom of the other macrocycle, the co-ordination geometry about each metal ion being pentagonal pyramidal.Keywords
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