SYNTHESES AND REACTIVITY OF NEW P-H DIBENZOBICYCLIC PHOSPHORANES BEARING HYDROXY-, ALKOXY-, OXO-, AMIDO-, AND DIHYDRIDO-FUNCTIONS AT THE PHOSPHORUS ATOM
- 1 July 1990
- journal article
- research article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 53 (1) , 87-101
- https://doi.org/10.1080/10426509008038016
Abstract
A series of new dibenzophosphoranes (1-6) bearing uncommon functions such as hydroxy-, alkoxy-, oxo-, amide- and dihydride- attached to the phosphorus atom have been prepared and characterized. The reactivities of the alkoxy derivative 1 and the amide 2 towards alcohols, amines, water and borane were studied mainly by 31P NMR. The structure of the diphenoxyamine-bis-phoshorane 4 was established by single crystal X-ray diffraction studies.Keywords
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