Matrix Isolation Infrared Spectra of Methylacetate. I. Monomer and Dimer Absorptions in Argon
- 1 April 1983
- journal article
- research article
- Published by Taylor & Francis in Spectroscopy Letters
- Vol. 16 (4) , 311-324
- https://doi.org/10.1080/00387018308062348
Abstract
The infrared spectrum of methylacetate is presented in argon matrices at 12 K. An assignment of monomer and dimer absorptions is proposed. The ester molecules are believed to be H-bonded in the dimer system.Keywords
This publication has 24 references indexed in Scilit:
- Rotational isomerism in methyl formate and methyl acetate; a low-temperature matrix infrared study using thermal molecular beamsChemical Physics Letters, 1981
- Conformational analysis—CXXIIITetrahedron, 1977
- Molecular Structure and Composition of Gaseous Methyl Formate as Determined by Electron Diffraction.Acta Chemica Scandinavica, 1977
- Nuclear magnetic resonance spectroscopy. Carbon-13 chemical and carbon-13 proton couplings in some esters and ethersThe Journal of Organic Chemistry, 1975
- Electric dipole moment studies of carboxylic ester conformations: alkyl acetates, benzoates, 2,4,6-trimethyl-benzoates and 2,3,5,6-tetramethylbenzoatesJournal of Molecular Structure, 1975
- Conformational behaviour and vibrational spectra of methyl propionateChemical Physics Letters, 1974
- Vibrational spectra and structure of esters—I. Infrared and Raman spectra of CH3COOCH3, CH3COOCD3, CD3COOCH3 and CD3COOCD3Spectrochimica Acta Part A: Molecular Spectroscopy, 1974
- Dielectric Relaxation and Molecular Structure. VIII. Dielectric Relaxation of Alkyl Acetates in Benzene SolutionBulletin of the Chemical Society of Japan, 1974
- Molecular structure and conformation of carboxylic estersJournal of Molecular Structure, 1973
- Stable carbonium ions. XLIV. Cleavage of protonated aliphatic carboxylic acids to alkyloxocarbonium ionsJournal of the American Chemical Society, 1967