Hard-Sphere Model of Binary Liquid Mixtures
- 1 October 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 47 (7) , 2248-2255
- https://doi.org/10.1063/1.1703300
Abstract
An equation of state [Eq. (2) of the text] which has been successfully applied to pure liquids composed of small, nonpolar molecules was generalized to the case of binary mixtures. The generalized equation was used to calculate excess thermodynamic functions for 10 equimolar mixtures, and agreement with experiment was found to be generally good. The partial molar heat of solution of gaseous neon in liquid argon was also calculated, but good agreement with experiment was not obtained in this calculation.Keywords
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