Reaction of Methyl (pyrrolidino)chromium Carbene Complex with Epoxides: Synthesis of γ-Hydroxyalkyl(pyrrolidino)chromium Carbene Complexes
- 1 January 1992
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1992 (04) , 315-316
- https://doi.org/10.1055/s-1992-21997
Abstract
A series of new hydroxyalkyl(pyrrolidino)chromium carbene complexes 3a-f have been synthesized in good yields through the ring-opening reaction of epoxides 2a-e promoted by the conjugate base of methyl(pyrrolidino)chromium carbene (1), in the absence or in the presence of diethyl ether-boron trifluoride complex.Keywords
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