C 1sautoionization study of electron hopping rates in solid
- 29 November 1993
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 71 (22) , 3721-3724
- https://doi.org/10.1103/physrevlett.71.3721
Abstract
We present C 1s autoionization studies of condensed and Xe matrix-isolated molecules which give direct information on electron hopping rates in solid in the presence of a C 1s vacancy. These rates vary dramatically for the first three C 1s absorption excitation maxima in a pattern consistent with strong electron-electron correlations. Hopping associated with the second excited state involves extramolecular screening comparable to the Mott-Hubbard pseudogap predicted for , suggesting intramolecular correlations do not dominate electron transport in the alkali fullerides.
Keywords
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