Effects of Electrochemical Activation and Multiwall Carbon Nanotubes on the Capacitive Characteristics of Thick MnO[sub 2] Deposits

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Abstract
[[abstract]]©2004 Electrochem - Thick composites composed of crystalline manganese dioxide (MnO2) and multiwall carbon nanotubes (MWCNTs) were successfully codeposited onto a graphite substrate from an Mn(AcO)2·4H2O+MWCNTs solution. The rate/nucleation mechanism of MnO2 deposition was significantly influenced by the introduction of MWCNTs in the plating baths. The specific capacitance of thick MnO2-MWCNT composites, measured from cyclic voltammetry (CV) or chronopotentiometry (CP) in a potential window of 1.0 V, is monotonously decreased from ca. 160 to 80 F/g with increasing the oxide loading from 1.5 to 4.5 mg/cm2. The lower specific capacitance of thick MnO2 and MnO2-MWCNTs deposits is reasonably attributed to the relatively poorer utilization of electroactive species as well as the compact structure in comparison with a thin Mn oxide deposit (<1 μm). The capacitive performance of these thick MnO2 deposits in 0.1 M Na2SO4 is significantly improved by the application of electrochemical activation and the introduction of MWCNTs, revealing the promising improvement in the capacity of electrodes[[department]]化學工程學