Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide
- 21 June 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 14,p. 2797-2799
- https://doi.org/10.1039/b204560e
Abstract
The complexes [Co(TCT)(OR)]BPh4 (R = Et, Ph; TCT = cis,cis-1,3,5-tris(cinnamylideneamino)cyclohexane) have been prepared and characterised by X-ray diffraction; in coordinating solvents both complexes react reversibly with carbon dioxide to form organocarbonate complexes.Keywords
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