Four-, five-, and six-co-ordinate cationic isonitrile cationic isonitrile complexes of rhodium and iridium
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1197-1198
- https://doi.org/10.1039/c29710001197
Abstract
The isonitrile complexes, [M(CNR)4]+, [M(PPh3)2(CNR)2]+, and [M(PPh3)2(CNR)3]+(M = Rh or Ir; R = alkyl or aryl) have been prepared, and undergo oxidative-addition reactions giving [M(CNR)4XY]+[M(PPh3)2(CNR)2XY]+, [M(PPh3)2(CNR)3X]2+, and [M(PPh3)2(CNR)2Y2]+, (X = halogen, methyl, acyl, allyl, HgCl, SnCl3; Y = halogen).Keywords
This publication has 0 references indexed in Scilit: