Structural distortions in Pd–MeO-Biphep and Pd–Binap aryl complexes. Anomalies induced via electronic effects
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 14,p. 2279-2280
- https://doi.org/10.1039/a903509e
Abstract
The four-coordinate complexes [PdBr(p-NCC6H4)(MeO-Biphep)], 1 [MeO-Biphep = 6,6′-dimethoxy-2,2′-bis(diphenylphosphino)-1,1′-biphenyl], and [PdBr(p-NCC6H4)(p-tol-Binap)], 2 [p-tol-Binap = 2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl], both distort markedly, with the former no longer square-planar, and the latter, possessing the longest recorded Pd–P bond length.Keywords
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