Hypophosphite mediated carbon–carbon bond formation: total synthesis of epialboatrin and structural revision of alboatrin
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 21,p. 3071-3073
- https://doi.org/10.1039/a907032j
Abstract
1-Ethylpiperidine hypophosphite (1-EPHP) has been used in the key radical-cyclisation step in a 6-step synthesis of the phytotoxic metabolite alboatrin and its epimer from orcinol. The synthesis demonstrates that the stereochemistry of the structure initially proposed for alboatrin requires revision.Keywords
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