Solubility of hydrogen in liquid aluminium
- 1 January 1988
- journal article
- research article
- Published by SAGE Publications in Materials Science and Technology
- Vol. 4 (1) , 1-4
- https://doi.org/10.1179/026708388790329738
Abstract
The solubility of hydrogen in liquid pure aluminium has been redetermined for temperatures from 943 to 1123 K and pressures from 67 to 113 kPa (0·66 to 1·12 atm), using an appropriate version of Sieverts' method. The results fit the Van't Hoff isobar and Sieverts' isotherm. Recommended values for the solubility (S) are given, based on critical assessment of both the present results and corresponding results from recent previous determinations. The recommended values are given by the equation log(S/S°)−1/2log(p/p°)=(−2700/T)+2·72, where S° is a standard value of solubility equal to 1 cm3 of diatomic hydrogen measured at 273 K and 101·325 kPa (1 atm) per 100 g of metal, p° is a standard pressure equal to 101·325 kPa (1 atm), and T is absolute temperature. MST/502Keywords
This publication has 5 references indexed in Scilit:
- Embedded-atom method: Derivation and application to impurities, surfaces, and other defects in metalsPhysical Review B, 1984
- Covalent effects in the effective-medium theory of chemical binding: Hydrogen heats of solution in themetalsPhysical Review B, 1982
- Atoms embedded in an electron gas: Immersion energiesPhysical Review B, 1981
- Quasiatoms: An approach to atoms in nonuniform electronic systemsPhysical Review B, 1980
- The solubility of hydrogen in molten aluminiumTransactions of the Faraday Society, 1935