Fabrication of Refractive Index Profiles in Poly (Methyl Methacrylate) using Ultraviolet Rays Irradiation

Abstract
We demonstrated that the refractive index of poly(methyl methacrylate) (PMMA) increased by simple ultraviolet rays irradiation. The index change, +1.0% was due to the change of chemical structure including elimination of the carbonyl group, followed by olefin formation, which were determined by Fourier-transform infrared rays and UV absorption spectra. A refractive index profile for 15-µm-thick PMMA was realized by irradiation for 4 h. Therefore, it is considered that the graded index (GI) profile of PMMA can be applied to microdevices such as a microspherical lens, single-mode waveguide and so on.

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