Racemisation behaviour of trinuclear helicates formed from ethylene-bridged tris(catechol) ligands and titanium(IV) ions

1 January 1998

journal article
research article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 1,p. 137-138
https://doi.org/10.1039/a705663j

Abstract

Trinuclear helicates are self-assembled from ligand H₆L¹ and Ti^IV ions in the presence of sodium or potassium carbonate and they racemise by consecutive inversion of the three complex units.

Keywords

SODIUM
TRINUCLEAR HELICATES
RACEMISATION
H6L1
TRIS
TITANIUM
CONSECUTIVE

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