Wittig rearrangements of allyl vinylcyclopropylmethyl ethers
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 684-685
- https://doi.org/10.1039/c39760000684
Abstract
Anions derived from allyl vinylcyclopropyl-methyl ethers (2) rearrange by competing [1,2], [1,4], homo [2,5], and homo [4,5] sigmatropic changes to give allylic alcohols (4) and (9) and aldehydes (5) and (6); the hydrocarbon (8) results from a radical dissociation-recombination process.Keywords
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