Mößbauer- und Raman-Spektren von Fe(O2PF2)3 und Fe(O2PCl2)3 / Mössbauer- and Raman-Spectra of Fe (O2PF2) 3 and Fe (O2PCl2)3
Open Access
- 1 August 1971
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 26 (8) , 747-750
- https://doi.org/10.1515/znb-1971-0802
Abstract
From Mössbauer spectra of Fe (O2PF2)3 and Fe (O2PCl2) follows a distortion of the symmetric octahedral environment of Fe (III). Whereas in Fe (O2PCl2)3 only O-Atoms are ligands of Fe (III) in Fe (O2PF2) 3 both O- and F-Atoms have ligand-functions. Simple ionic forces between Fe (III) and the Dihalogenphosphatogroups are excluded as a result of Raman spectra.Keywords
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