Macrocyclic tetramanganese(II) complexes with alkoxy and chloro or azido bridges; X-ray crystal structures of [Mn2(HL)(Cl)2]2(ClO4)2·2dmf·H2O and [Mn2(HL)(N3)2]2(ClO4)2·3MeCN (H2L = 1,7,14,20-tetramethyl-2,6,15,19-tetra-aza[7,7](2,6)pyridinophane-4,7-diol; dmf = dimethylformamide)
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 619-620
- https://doi.org/10.1039/c39890000619
Abstract
Two tetranuclear MnII complexes are described; complex (1) incorporates both oxygen and chlorine bridging atoms as postulated for the oxygen evolving complex of photosystem II.Keywords
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