A dual regiocontrol in the copper-catalysed Grignard reaction with primary allylic acetates
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 827-829
- https://doi.org/10.1039/c39870000827
Abstract
The reaction of primary allylic acetates with Grignard reagents in the presence of catalytic amounts of Li2CuCl4 can be regiochemically controlled to give either α- or γ-substitution of the allylic acetoxy group.Keywords
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