The rhodium catalysed co-oxygenation of cis-cyclo-octene
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1313-1315
- https://doi.org/10.1039/c39840001313
Abstract
Deuterium labelling studies show that, contrary to earlier proposals, at a rhodium centre of cis-cyclo-octeme into the allylic alcohol, cyclo-oct-2-en-1-ol (1) involved oxygenative attack at a vinylic centre and double bond migration; a finding considered to have mechanistic implications for related co-oxygenations at group 8 metal centres.Keywords
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