Unified derivation of the perturbation series for the real and imaginary parts of the energy of hydrogen in the stark effect and of the negatively anharmonic oscillator
- 1 January 1982
- journal article
- research article
- Published by Wiley in International Journal of Quantum Chemistry
- Vol. 21 (1) , 125-131
- https://doi.org/10.1002/qua.560210109
Abstract
The wave function for hydrogen in the Stark effect (or for the negatively anharmonic oscillator) with an outgoing‐wave boundary condition, constructed in Langer‐Cherry fJWKB form, is continued back to the origin. The asymptotic expansions for ReE and ImE are determined by the requirement that the wave function be regular at the origin to zeroth and first order in the exponentially small parameter that characterizes ImE. One fJWKB function turns out to be the Rayleigh‐Schrödinger perturbation theory wave function.Keywords
This publication has 6 references indexed in Scilit:
- High-order perturbation theory of the imaginary part of the resonance eigenvalues of the Stark effect in hydrogen and of the anharmonic oscillator with negative anharmonicityPhysical Review A, 1981
- New method of perturbation-theory calculation of the Stark effect for the ground state of hydrogenPhysical Review A, 1980
- Stark effect in hydrogen: High orders of perturbation theory for excited statesPhysics Letters A, 1980
- The high orders of perturbation theory for the stark effect in hydrogenPhysics Letters A, 1979
- New Approach to Perturbation TheoryPhysical Review Letters, 1979
- Modified perturbation theories for an anharmonic oscillatorPhysics Letters B, 1978