A Mild and Efficient Method for the Cleavage of tert-Butyldimethylsilyl and Tetrahydropyranyl Ethers by Ceric Ammonium Nitrate in Methanol
- 1 January 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (01) , 69-71
- https://doi.org/10.1055/s-1996-5320
Abstract
A variety of tert-butyldimethylsilyl (TBDMS) and tetrahydropyranyl (TFP) ethers were cleaved with ceric ammonium nitrate in methanol at 0 °C in short time. It has been shown that the reaction is chemoselective in a few cases. The primary TBDMS ethers have been cleaved selectively in the presence of THP ether and ketal.Keywords
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