Photokatalytische Systeme. XIV. Über den Mechanismus der Photooxydation von Alkoholen mittels Uranylnitrat
- 1 August 1978
- journal article
- research article
- Published by Wiley in Zeitschrift für anorganische und allgemeine Chemie
- Vol. 443 (1) , 255-264
- https://doi.org/10.1002/zaac.19784430128
Abstract
Die bei der Photolyse von UO2(NO3)2 · 6 H2O in Methylenchlorid‐Alkohol‐Gemischen entstehenden Radikale wurden mittels ESR‐Spin‐Trapping untersucht. Neben dem Angriff des photoangeregten Uranylions an der α‐CH‐Bindung des Alkohols spielen Elektronentransferprozesse eie Rolle.Keywords
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