Stereoselective synthesis of Z-enol esters catalysed by [bis(diphenylphosphino)alkane]bis(2-methylpropenyl)ruthenium complexes
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 850-851
- https://doi.org/10.1039/c39930000850
Abstract
Z-Enol esters are obtained via region- and stereo-selective addition of carboxylic acids to terminal alkynes, with formation of a C(1) carbon–oxygen bond, in the presence of a [Ru{Ph2P(CH2)nPPh2}{η3-CH2–C(Me)CH2}2] catalyst precursor.Keywords
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