Glassy behavior of crystalline solids at low temperatures

Abstract
Measurements of low-temperature specific heat C, thermal conductivity κ, and dielectric dispersion have been made on crystalline samples of the superionic conductor Li3N, the oxygen conductor Y2 O3-stabilized ZrO2, and the relaxation ferroelectric Pb3 (MgNb2)O9. In each case, the behavior is similar to that found in amorphous materials. Data on other crystalline materials are reviewed to emphasize that the low-temperature phenomena found in glasses can occur in crystals. It is shown that a peak in CT3 appears to be correlated, in both amorphous and crystalline materials, with a nearly temperature-independent regime (plateau) in κ.