Effect of rotations on degenerate vibrations of the nitrate ion
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 71, 1440-1447
- https://doi.org/10.1039/f29757101440
Abstract
Rotational-vibrational infrared and Raman spectra have been calculated for the degenerate modes of a hypothetical free nitrate ion. Comparison of the computed spectra with results obtained for the nitrate ion in aqueous solution indicates that rotational motions are not the primary cause of the doublet structure of the ν3(E′) band.Keywords
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