meso-Octamethyl-porphyrinogen metal complexes: an entry to high valent unsaturated metal centres

Abstract
The meso-octamethyl porphyrinogen tetraanion has been used to bind iron(III) and oxomolybdenum(V) ions; X-ray analysis revealed the interaction of a square-planar tetracoordinate FeIII and the oxo group in the MoV complex with the meso-methyls.

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