Entropy of intercalation compounds. II. Calorimetry of electrochemical cells of the Chevrel compound LixMo6Se8for 0⩽x⩽4
- 20 September 1986
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 19 (26) , 5135-5148
- https://doi.org/10.1088/0022-3719/19/26/013
Abstract
For pt.I see ibid., vol.19, p.5121 (1986). The authors describe the first calorimetric measurements of the entropy of an intercalation compound. A lattice gas model of intercalation describes the variation of ( delta s/ delta x)T with x in LixMo6Se8 for x1, ( delta s/ delta x)T shows features associated with phase transitions, and the shape of these features distinguishes continuous transitions from first-order transitions.Keywords
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