Local modes of , , and pairs in KBr, KI, NaCl, and RbCl
- 15 June 1974
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 9 (12) , 5257-5263
- https://doi.org/10.1103/physrevb.9.5257
Abstract
The main coupling between localized or harmonic oscillators in KCl, KBr, KI, NaCl, and RbCl is confirmed to be the dipole-dipole interaction. Several configurations for the or pairs were detected and their mode frequencies were found to be in accordance with the dipole-dipole interaction. The absorption line of one of the transverse modes of the neighboring pairs in KBr was found to be composed of four peaks. This structure is shown to be related to critical points in the phonon dispersion curves of the pure KBr crystal. The approach to the pair-mode linewidth proposed in a previous paper is shown to be valid in its general features.
Keywords
This publication has 6 references indexed in Scilit:
- Infrared Absorption of Pairs of Coupled Local-Mode Oscillators: , , and Pairs in KClPhysical Review B, 1973
- Polarized Local-Mode Absorption of Aligned , , and Pairs in Alkali HalidesPhysical Review Letters, 1970
- Lattice Dynamics of NaCl, KCl, RbCl, and RbFPhysical Review B, 1970
- Infrared absorption due to H− ions in sodium and potassium halides. I. Anharmonic side bands of the local modeCanadian Journal of Physics, 1970
- Infrared Absorption and Anharmonicity of the U‐Centre Local Mode. I. ExperimentsPhysica Status Solidi (b), 1965
- Lattice Dynamics and Specific-Heat Data for Rocksalt-Structure Alkali HalidesPhysical Review B, 1963