Novel one-pot synthesis of 1-iodo-1-trimethylsilyl 1,3-dienes
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 3,p. 389-391
- https://doi.org/10.1039/p19930000389
Abstract
Iodine was added to 3-(trimethylsilyl )allylic phosphonium ylide regiospecifically to give 3-iodo-3-trimethylsilyl allylic phosphonium ylide, which reacted with carbonyl compounds to give 1-iodo-1-trimethylsilyl 1,3-dienes with high stereoselectivity in good yield.Keywords
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