Biogenetic-like rearrangements of isosteviol derivatives: π-route to the atiserene system
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 14,p. 797-798
- https://doi.org/10.1039/c29690000797
Abstract
Solvolytic cyclization of the unsaturated tricyclic toluene-p-sulphonate (IV) affords the atiseran-13-ol derivative (VI), which at higher temperature undergoes Wagner–Meerwein rearrangement to the hibaan-12-ol isomer (IX).Keywords
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