Simple surface ionization detector with field reversal for absolute ionization coefficient and ionic and neutral desorption measurements
- 1 September 1976
- journal article
- research article
- Published by AIP Publishing in Review of Scientific Instruments
- Vol. 47 (9) , 1167-1171
- https://doi.org/10.1063/1.1134793
Abstract
Recent absolute reactive scattering experiments have demonstrated the need for and usefulness of absolute flux measuring molecular beamdetectors. A field reversal detector of the type described here can conveniently and accurately (<±3%) measure the absolute flux of molecular beams of easily ionizable substances, without external calibrations or surface condition or surface temperature changes. The detector is mechanically very similar to the common surface ionizationdetector and uses uncomplicated electronics. With such a detector the neutral and ionic desorption rates may also be accurately determined separately. Thus the values of the true desorption parameters may be measured; such values have usually not been produced by previous methods for desorption rate measurements.Keywords
This publication has 10 references indexed in Scilit:
- Surface ionization molecular beam detector with a magnetic mass filter: application to absolute differential reactive cross section measurementsJournal of Physics E: Scientific Instruments, 1976
- Molecular beam surface ionization detection: I. Absolute ionization coefficients and work function of “low work function” Pt(8%W) surfacesSurface Science, 1976
- Molecular beam scattering experiments on the reaction K + RbCl: Absolute angular distributions and integral cross sectionsThe Journal of Chemical Physics, 1974
- Surface Lifetimes of Alkali Metals on MolybdenumThe Journal of Chemical Physics, 1971
- Residence time measurements for the surface ionization of K on W: The effects of surface contaminantsSurface Science, 1970
- Positive Surface Ionization of Na, NaCl, NaBr, NaI, and LiCl on Rhenium and on Oxygenated Rhenium SurfacesThe Journal of Chemical Physics, 1969
- Mean Residence Times of Alkali Ions on Polycrystalline Wolfram Surfaces as Studied with a Pulsed‐Molecular‐Beam Mass SpectrometerAnnalen der Physik, 1966
- Kinetics of Cs+ Desorption from TungstenThe Journal of Chemical Physics, 1962
- Mean Adsorption Lifetime of Rb on Etched Tungsten Single Crystals: NeutralsPhysical Review B, 1959
- The positive ion work function of tungsten for the alkali metalsProceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1933