Brominative cleavage of α-ketols
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1875-1876
- https://doi.org/10.1039/p19720001875
Abstract
Bromination of some α-ketols resulted in cleavage of the carbonyl–carbinol bond; 1-hydroxy-1,1 -diphenylacetone, for example, gave benzophenone. Bromination of diphenyl-substituted tertiary alcohols does not cause degradation and the products are bromohydrins and/or substituted alkenes.Keywords
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