Investigation of the Electrochemical Characteristics of Organic Compounds

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Abstract
Anodic half‐cell potential discharge data are presented for various classes of organic sulfur compounds, such as the thiophenols, mercaptans, and thioureas in alkaline electrolyte. The effect of group substitution and aromaticity on the anode potential of the thiophenol compounds is interpreted in terms of the electron density distribution in the molecule. Half‐cell potential discharge data for the reversible thiourea‐formamidine disulfide and dithiobiuret‐thiuret systems in different electrolytes of varying pH are also presented.

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