Preparation of 1-methyl-2,2-diphenylcyclopropylcobaloxime and theoretical considerations for its mode of formation
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 153-154
- https://doi.org/10.1039/c39730000153
Abstract
The title compound, which contains a stable tertiary alkylcobalt σ-bond, is readily obtained from the reaction of pyridine[bis(dimethylglyoximato)]cobalt(I) and 1-methyl-2,2-diphenylcyclopyl bromide; five mechanisms for the reactions of low-valent metal ions and alkyl halides are discussed.Keywords
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