A synthetic approach to the pseudopterosins
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1743-1744
- https://doi.org/10.1039/cc9960001743
Abstract
Three Lewis acid catalysed reactions used in a synthesis of the tricyclic core of the marine anti-inflammatory pseudopterosins are reported; the reductive cleavage of an oxirane with inversion, the cyclisation of an α-hydroxy ketenedithioacetal to an arene, and a stereoselective annulation using an allylic sulfone as the electrophile.Keywords
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