Conversion of the olivanic acids into antibiotics of the PS-5 type: use of a new carboxy protecting group
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1083-1084
- https://doi.org/10.1039/c39800001083
Abstract
The syntheses of PS-5 (1) and analogues from the olivanic acids MM 17880 (4) and MM 13902 (10), including the use of a new carboxy protecting group, the p-methoxycarbonylbenzyl group, are reported together with the chemical elucidation of the stereochemistry at C-8 of the olivanic acids.Keywords
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