Solid-state solvolysis induced via charge-transfer complexation by solid-phase grinding followed by contact with solvent vapor
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 1965-1966
- https://doi.org/10.1039/a803496f
Abstract
When 9-thienothienylfluoren-9-ol derivatives were ground together with DDQ then exposed to methanol vapor, solvolysis occurred to yield 9-methoxyfluorenes via the generation of a radical cation by solid-state single-electron transfer.Keywords
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