The effect of stereochemistry on 1JC—H at the sp2 carbons of oxime, hydrazone, and imine derivatives of aldehydes
- 1 March 1983
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 61 (3) , 576-578
- https://doi.org/10.1139/v83-102
Abstract
A comparison of the magnitudes of 1JC—H at the aldehydic carbon of both the syn and anti isomers of aldehyde derivatives (oximes, hydrazones, and imines) has shown a consistently greater value, by about 20 Hz, for the syn isomer. Regardless of its origin, this stereochemical correlation should prove useful in providing configurational assignments.Keywords
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