β-Substituted cyclopropyl radicals

1 January 1983

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 12,p. 685-687
https://doi.org/10.1039/c39830000685

Abstract

Ab initio and MNDO molecular orbital calculations support experimental evidence that 2-metallo-substituted cyclopropyl radicals prefer cis- while 2-halogenocyclopropyl radicals prefer trans-configurations.

Keywords

SUBSTITUTED CYCLOPROPYL
RADICALS PREFER
EXPERIMENTAL
TRANS
CONFIGURATIONS
METALLO