Observations of polymetal carbonyl cations in the mass spectra of the group VI metal hexacarbonyls
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 3,p. 159-161
- https://doi.org/10.1039/c29710000159
Abstract
Secondary ions, Mm(CO)n +, considered to arise from ion–molecule reactions, have been observed in the mass spectra of Cr(CO)6, Mo(CO)6, and W(CO)6 at 10–5–10–6 Torr at 35–100°; depending upon m(1–3 for Cr, 1–2 for Mo, and 1–4 for W) the value of n is 0–14.Keywords
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