Kinetics of the Oxidation of Acrolein Initiated by Di-t-Butyl Diperoxyoxalate
- 1 January 1974
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 47 (1) , 156-159
- https://doi.org/10.1246/bcsj.47.156
Abstract
The kinetics of the liquid-phase autoxidation of acrolein were studied using di-t-butyl diperoxyoxalate as an initiator. The ratios of the rate constants for the propagation vs the termination steps (k3k6−1⁄2 and k2k4−1⁄2) in the autoxidation mechanism were determined from the empirical rate equation thus obtained. The lower reactivity of acrolein was explained by comparing the ratios with those of saturated aldehydes.Keywords
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