Structure and Reactivity of Lithium Diisopropylamide Solvated by Polyamines: Evidence of Monomer- and Dimer-Based Dehydrohalogenations
- 22 April 1998
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 120 (17) , 4081-4086
- https://doi.org/10.1021/ja9741279
Abstract
No abstract availableKeywords
This publication has 24 references indexed in Scilit:
- Lithium 2,2,6,6-Tetramethylpiperidide and Lithium 2,2,4,6,6-Pentamethylpiperidide: Influence of TMEDA and Related Chelating Ligands on the Solution Structures. Characterization of Higher Cyclic Oligomers, Cyclic Dimers, Open Dimers, and MonomersThe Journal of Organic Chemistry, 1997
- Chelation-Based Stabilization of the Transition Structure in a Lithium Diisopropylamide Mediated Dehydrobromination: Avoiding the “Universal Ground State” AssumptionJournal of the American Chemical Society, 1997
- Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide (LiHMDS)Journal of the American Chemical Society, 1996
- Benzylic Lithium Compounds: The Missing Link in Carbon-Lithium Covalency. Dynamics of Ion Reorientation, Rotation around the Ring-Benzyl Bond, and Bimolecular C-Li ExchangeJournal of the American Chemical Society, 1995
- Metalation of imines by lithium diisopropylamide solvated by N,N,N',N'-tetramethylethylenediamine: evidence for solvent-free open dimer reactive intermediatesJournal of the American Chemical Society, 1993
- Structure and reactivity of lithium diisopropylamide (LDA) in hydrocarbon solutions. Formation of unsolvated ketone, ester, and carboxamide enolatesThe Journal of Organic Chemistry, 1991
- Stereochemistry of LiNR2-induced 1,4-elimination of allylic (benzylic) ethersThe Journal of Organic Chemistry, 1986
- Acidity measurements with lithiated amines: steric reduction and electronic enhancement of acidityThe Journal of Organic Chemistry, 1984
- Lithium Complexes with pentahapto‐Bonded Cyclopentadienyl LigandsAngewandte Chemie International Edition in English, 1983
- A convenient method for estimation of alkyllithium concentrationsThe Journal of Organic Chemistry, 1976