A short synthesis of (+)-isophyllocladene and (+)-phyllocladene
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 282
- https://doi.org/10.1039/c39750000282
Abstract
Rearrangement of the ketone (4) obtained by photochemical cycloaddition of allene to Δ8(14)-podocarpen-13-one (5) leads to (+)-Δ15-isophyllocladen-14-one (3), which can be converted into (+)-isophyllocladene (2) or (+)-phyllocladene (1).Keywords
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