The atomic heats of the rare-earth elements
- 22 June 1951
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 207 (1089) , 137-155
- https://doi.org/10.1098/rspa.1951.0108
Abstract
The discussion of molecular orbitals and equivalent orbitals, given in previous papers, is carried a stage further. It is shown that certain molecular properties can be evaluated using either equivalent or molecular orbitals. On the other hand, a study of the changes produced by ionization demonstrates that molecular orbitals have a special significance and that certain energy parameters associated with them are closely related to ionization potentials. For the purpose of this discussion a perturbation theory is developed to deal with the changes produced in molecular systems when disturbed from their normal states.Keywords
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