The synthesis and structural characterization of [ReCl2(PPh3)2(NNHCOPh)(NHNHCOPh)]·1/2Et2O, a complex exhibiting linear hydrazido(2–) ligation and end-on hydrazido(1–) ligation
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 367-368
- https://doi.org/10.1039/c39850000367
Abstract
The title ocmpound was prepared by treating [ReCl2(PPh3)2(NNCOPh)] with excess of benzoylhydrazine in methanol Solution: X-ray crystallography reveals a unique example of monohapto-co-ordination by a hydrazido(1–) grouping, –NHNHR, and an unusual instance of mixed hydrazido(2–) and hydrazido(1–) co-ordination to a metal site.Keywords
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